| Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation | |
| Wusiman Abudureheman; Tusun Xiarepati; Lu Chong-Dao; Lu, CD | |
| 2012 | |
| Source Publication | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| ISSN | 1434-193X |
| Issue | 16Pages:3088-3092 |
| Abstract | A new class of dirhodium(II) tetraamidinates derived from 2-(sulfonylimino)pyrrolidines has been prepared through ligand substitution by using dirhodium(II) acetate, in which (3,1) geometric isomers are formed predominantly. Among these complexes, (3,1)-Rh2(Msip)4, exhibits good catalytic performance in benzylic oxidation. In the presence of (3,1)-Rh2(Msip)4 a variety of benzylic derivatives, including strongly electron-deficient arylalkanes such as 1-ethyl-4-nitrobenzene, are readily oxidized in water by the inexpensive oxidant T-HYDRO (R) (70 wt.-% aqueous tert-butyl hydroperoxide). |
| Keyword | Rhodium n Ligands Bridging Ligands Homogeneous Catalysis Benzylic Oxidation |
| Subject Area | Chemistry |
| DOI | 10.1002/ejoc.201200292 |
| Indexed By | SCI |
| WOS ID | WOS:000304083700007 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.xjipc.cas.cn/handle/365002/1626 |
| Collection | 资源化学研究室 |
| Corresponding Author | Lu, CD |
| Affiliation | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Normal Univ, Sch Chem & Chem Engn, Urumqi 830054, Peoples R China |
| Recommended Citation GB/T 7714 | Wusiman Abudureheman,Tusun Xiarepati,Lu Chong-Dao,et al. Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(16):3088-3092. |
| APA | Wusiman Abudureheman,Tusun Xiarepati,Lu Chong-Dao,&Lu, CD.(2012).Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(16),3088-3092. |
| MLA | Wusiman Abudureheman,et al."Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .16(2012):3088-3092. |
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| dirhodium(ii) comple（377KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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