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Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation
Wusiman Abudureheman; Tusun Xiarepati; Lu Chong-Dao; Lu, CD
2012
Source PublicationEUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN1434-193X
Issue16Pages:3088-3092
AbstractA new class of dirhodium(II) tetraamidinates derived from 2-(sulfonylimino)pyrrolidines has been prepared through ligand substitution by using dirhodium(II) acetate, in which (3,1) geometric isomers are formed predominantly. Among these complexes, (3,1)-Rh2(Msip)4, exhibits good catalytic performance in benzylic oxidation. In the presence of (3,1)-Rh2(Msip)4 a variety of benzylic derivatives, including strongly electron-deficient arylalkanes such as 1-ethyl-4-nitrobenzene, are readily oxidized in water by the inexpensive oxidant T-HYDRO (R) (70 wt.-% aqueous tert-butyl hydroperoxide).
KeywordRhodium n Ligands Bridging Ligands Homogeneous Catalysis Benzylic Oxidation
Subject AreaChemistry
DOI10.1002/ejoc.201200292
Indexed BySCI
WOS IDWOS:000304083700007
Citation statistics
Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1626
Collection资源化学研究室
Corresponding AuthorLu, CD
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Normal Univ, Sch Chem & Chem Engn, Urumqi 830054, Peoples R China
Recommended Citation
GB/T 7714
Wusiman Abudureheman,Tusun Xiarepati,Lu Chong-Dao,et al. Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(16):3088-3092.
APA Wusiman Abudureheman,Tusun Xiarepati,Lu Chong-Dao,&Lu, CD.(2012).Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(16),3088-3092.
MLA Wusiman Abudureheman,et al."Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .16(2012):3088-3092.
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