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学科主题: Chemistry
题名: Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation
作者: Wusiman Abudureheman; Tusun Xiarepati; Lu Chong-Dao
通讯作者: Lu, CD
关键词: Rhodium ; N ligands ; Bridging ligands ; Homogeneous catalysis ; Benzylic oxidation
刊名: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2012
DOI: 10.1002/ejoc.201200292
期: 16, 页:3088-3092
收录类别: SCI
资助者: National Natural Science Foundation of China 20972182, 21172251; "Western Light" program XBBS200820; Chinese Academy of Sciences
摘要: A new class of dirhodium(II) tetraamidinates derived from 2-(sulfonylimino)pyrrolidines has been prepared through ligand substitution by using dirhodium(II) acetate, in which (3,1) geometric isomers are formed predominantly. Among these complexes, (3,1)-Rh2(Msip)4, exhibits good catalytic performance in benzylic oxidation. In the presence of (3,1)-Rh2(Msip)4 a variety of benzylic derivatives, including strongly electron-deficient arylalkanes such as 1-ethyl-4-nitrobenzene, are readily oxidized in water by the inexpensive oxidant T-HYDRO (R) (70 wt.-% aqueous tert-butyl hydroperoxide).
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1626
Appears in Collections:资源化学研究室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Normal Univ, Sch Chem & Chem Engn, Urumqi 830054, Peoples R China

Recommended Citation:
Wusiman Abudureheman,Tusun Xiarepati,Lu Chong-Dao. Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(16):3088-3092.
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文件名: dirhodium(ii) complexes of 2-(sulfonylimino)pyrrolidine synthesis and application in catalytic benzylic oxidation.pdf
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