Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation

doi:10.1002/ejoc.201200292

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	Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation
	Wusiman Abudureheman; Tusun Xiarepati; Lu Chong-Dao; Lu, CD
	2012
发表期刊	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN	1434-193X
期号	16 页码:3088-3092
摘要	A new class of dirhodium(II) tetraamidinates derived from 2-(sulfonylimino)pyrrolidines has been prepared through ligand substitution by using dirhodium(II) acetate, in which (3,1) geometric isomers are formed predominantly. Among these complexes, (3,1)-Rh2(Msip)4, exhibits good catalytic performance in benzylic oxidation. In the presence of (3,1)-Rh2(Msip)4 a variety of benzylic derivatives, including strongly electron-deficient arylalkanes such as 1-ethyl-4-nitrobenzene, are readily oxidized in water by the inexpensive oxidant T-HYDRO (R) (70 wt.-% aqueous tert-butyl hydroperoxide).
关键词	Rhodium n Ligands Bridging Ligands Homogeneous Catalysis Benzylic Oxidation
学科领域	Chemistry
DOI	10.1002/ejoc.201200292
收录类别	SCI
WOS记录号	WOS:000304083700007
引用统计	被引频次：15[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.xjipc.cas.cn/handle/365002/1626
专题	资源化学研究室
通讯作者	Lu, CD
作者单位	Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Normal Univ, Sch Chem & Chem Engn, Urumqi 830054, Peoples R China
推荐引用方式 GB/T 7714	Wusiman Abudureheman,Tusun Xiarepati,Lu Chong-Dao,et al. Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(16):3088-3092.
APA	Wusiman Abudureheman,Tusun Xiarepati,Lu Chong-Dao,&Lu, CD.(2012).Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(16),3088-3092.
MLA	Wusiman Abudureheman,et al."Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .16(2012):3088-3092.

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