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The Oxidative Acylnitroso Hetero-Diels-Alder Reaction Catalyzed by Dirhodium Caprolactamate
Tusun Xiarepati; Lu Chong-Dao; Lu, CD
2012
Source PublicationSYNLETT
ISSN0936-5214
Issue12Pages:1801-1804
AbstractAn effective protocol is described for the generation and in situ Diels-Alder trapping of acylnitroso derivatives. In this procedure, the oxidation of hydroxamic acid is efficiently catalyzed by dirhodium(II) caprolactamate with tert-butyl hydroperoxide (TBHP) in the presence of dienes at room temperature. Using this approach we obtained a variety of hetero-Diels-Alder cycloadducts in yields of up to 96% at 0.1 mol% catalyst loading.
KeywordCatalysis Oxidation Acylnitroso Diels-alder Reaction Dirhodium(Ii)
Subject AreaChemistry
DOI10.1055/s-0031-1289786
Indexed BySCI
WOS IDWOS:000306426500016
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1625
Collection资源化学研究室
Corresponding AuthorLu, CD
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Tusun Xiarepati,Lu Chong-Dao,Lu, CD. The Oxidative Acylnitroso Hetero-Diels-Alder Reaction Catalyzed by Dirhodium Caprolactamate[J]. SYNLETT,2012(12):1801-1804.
APA Tusun Xiarepati,Lu Chong-Dao,&Lu, CD.(2012).The Oxidative Acylnitroso Hetero-Diels-Alder Reaction Catalyzed by Dirhodium Caprolactamate.SYNLETT(12),1801-1804.
MLA Tusun Xiarepati,et al."The Oxidative Acylnitroso Hetero-Diels-Alder Reaction Catalyzed by Dirhodium Caprolactamate".SYNLETT .12(2012):1801-1804.
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