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学科主题: Chemistry
题名: The Oxidative Acylnitroso Hetero-Diels-Alder Reaction Catalyzed by Dirhodium Caprolactamate
作者: Tusun Xiarepati; Lu Chong-Dao
通讯作者: Lu, CD
关键词: catalysis ; oxidation ; acylnitroso ; Diels-Alder reaction ; dirhodium(II)
刊名: SYNLETT
发表日期: 2012
DOI: 10.1055/s-0031-1289786
期: 12, 页:1801-1804
收录类别: SCI
资助者: National Natural Science Foundation of China 20972182, 21172251; 'Western Light' program XBBS200820; Chinese Academy of Sciences
摘要: An effective protocol is described for the generation and in situ Diels-Alder trapping of acylnitroso derivatives. In this procedure, the oxidation of hydroxamic acid is efficiently catalyzed by dirhodium(II) caprolactamate with tert-butyl hydroperoxide (TBHP) in the presence of dienes at room temperature. Using this approach we obtained a variety of hetero-Diels-Alder cycloadducts in yields of up to 96% at 0.1 mol% catalyst loading.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1625
Appears in Collections:资源化学研究室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Tusun Xiarepati,Lu Chong-Dao. The Oxidative Acylnitroso Hetero-Diels-Alder Reaction Catalyzed by Dirhodium Caprolactamate[J]. SYNLETT,2012(12):1801-1804.
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文件名: the oxidative acylnitroso hetero-diels-alder reaction catalyzed by dirhodium caprolactamate.pdf
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