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学科主题: Chemistry
题名: synthesis, growth, crystal structure and optical properties of babibo4
作者: Dong Xiaoyu; Pan Shilie; Li Feng; Shi Yunjing; Zhou Zhongxiang; Zhao Wenwu; Huang Zhenjun
通讯作者: Pan, SL
关键词: Crystal structure ; Synthesis ; BaBiBO4
刊名: INORGANIC CHEMISTRY COMMUNICATIONS
发表日期: 2012
DOI: 10.1016/j.inoche.2012.06.019
卷: 23, 期:9, 页:109-112
收录类别: SCI
摘要: The single crystal of BaBiBO4 has been grown up to about 18 mm x 10 mm x 5 mm by the top-seeded solution growth method (TSSG) in the Bi2O3 flux system. BaBiBO4 crystallizes in the centrosymmetric orthorhombic space group Pnma with a = 8.5556(8) angstrom, b = 5.1569(5) angstrom, c = 9.6677(7) angstrom, Z=4. It is a three-dimensional framework structure built up of BiO5 polyhedra, BaO9 polyhedra and BO3 triangles. The BiO5 polyhedra and BO3 triangles form infinite one-dimensional chains along the crystallographic b axis. BO3 groups present in the sample were identified by Fourier transform infrared spectrum. UV-vis-IR transmittance spectrum of BaBiBO4 showed that it has a wide transmittance range from 310 nm to 3000 nm. (C) 2012 Elsevier B.V. All rights reserved.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1607
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Dong Xiaoyu,Pan Shilie,Li Feng,et al. synthesis, growth, crystal structure and optical properties of babibo4[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,23(9):109-112.
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文件名: Synthesis, growth, crystal structure and optical properties of BaBiBO4.pdf
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