Synthesis, crystal structure and properties of a new strontium cadmium diborate
Cao Jian; Gao Junyu; Pan Shilie; Yu Hongwei; Zhao Wenwu; Yang Zhihua
2012
发表期刊INORGANICA CHIMICA ACTA
ISSN0020-1693
卷号392期号:9页码:459-464
摘要

A new compound, SrCdB2O5, has been grown by the high temperature solution method from the SrO-Cd-B2O3 system for the first time. It crystallizes in the orthorhombic system, space group Pbca with unit-cell parameters a = 12.010(4) angstrom, b = 5.795(2) angstrom, c = 12.677(4) angstrom, Z = 8, volume = 882.4(5) angstrom(3). Its structure is solved by the direct methods and refined to R-1 = 0.0256 and wR(2) = 0.0727. The new structure contains an infinite three-dimensional matrix that is built from B2O5 units and CdO6 and SrO9 polyhedra. Spectrum properties, thermal analysis and theoretical calculations on electronic structure of SrCdB2O5 were reported.

关键词Srcdb2o5 Crystal Structure Diborate X-ray Diffraction
学科领域Chemistry
DOI10.1016/j.ica.2012.03.012
收录类别SCI
WOS记录号WOS:000308696200065
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1605
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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Cao Jian,Gao Junyu,Pan Shilie,et al. Synthesis, crystal structure and properties of a new strontium cadmium diborate[J]. INORGANICA CHIMICA ACTA,2012,392(9):459-464.
APA Cao Jian,Gao Junyu,Pan Shilie,Yu Hongwei,Zhao Wenwu,&Yang Zhihua.(2012).Synthesis, crystal structure and properties of a new strontium cadmium diborate.INORGANICA CHIMICA ACTA,392(9),459-464.
MLA Cao Jian,et al."Synthesis, crystal structure and properties of a new strontium cadmium diborate".INORGANICA CHIMICA ACTA 392.9(2012):459-464.
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