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学科主题: Chemistry
题名: Synthesis, crystal structure and properties of a new strontium cadmium diborate
作者: Cao Jian; Gao Junyu; Pan Shilie; Yu Hongwei; Zhao Wenwu; Yang Zhihua
通讯作者: Pan, SL
关键词: SrCdB2O5 ; Crystal structure ; Diborate ; X-ray diffraction
刊名: INORGANICA CHIMICA ACTA
发表日期: 2012
DOI: 10.1016/j.ica.2012.03.012
卷: 392, 期:9, 页:459-464
收录类别: SCI
资助者: National Natural Science Foundation of China;Chinese Academy of Sciences;Xinjiang Uygur Autonomous Region of China
摘要: A new compound, SrCdB2O5, has been grown by the high temperature solution method from the SrO-Cd-B2O3 system for the first time. It crystallizes in the orthorhombic system, space group Pbca with unit-cell parameters a = 12.010(4) angstrom, b = 5.795(2) angstrom, c = 12.677(4) angstrom, Z = 8, volume = 882.4(5) angstrom(3). Its structure is solved by the direct methods and refined to R-1 = 0.0256 and wR(2) = 0.0727. The new structure contains an infinite three-dimensional matrix that is built from B2O5 units and CdO6 and SrO9 polyhedra. Spectrum properties, thermal analysis and theoretical calculations on electronic structure of SrCdB2O5 were reported.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1605
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Cao Jian,Gao Junyu,Pan Shilie,et al. Synthesis, crystal structure and properties of a new strontium cadmium diborate[J]. INORGANICA CHIMICA ACTA,2012,392(9):459-464.
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文件名: synthesis, crystal structure and properties of a new strontium cadmium diborate.pdf
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