Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl
Wu Hongping; Pan Shilie; Yu Hongwei; Huang Zhenjun; Jia Dianzeng
2012
Source PublicationJournal of Molecular Structure
ISSN222860
Volume1027Issue:11Pages:111-115
Abstract

Introduction of the citric acid in the borate system generates a new phase, Ca[B(C6H6O7)2](H2O) 4s˙HCl, which is transparent from 195 nm to near infrared region. Single crystals of Ca[B(C6H6O7) 2](H2O)4s˙HCl with dimensions up to 7 × 5 × 2 mm3 were successfully grown by slow evaporation method at room temperature. It has been characterized by single crystal X-ray diffraction, infrared spectroscopy measure and thermogravimetric analysis. Ca[B(C6H6O7)2](H2O) 4s˙HCl crystallizes in the triclinic space group P - 1, with a = 6.3243(18) A˚, b = 8.365(2) A˚, c = 19.042(5) A˚, α = 97.291(3)°, β = 94.535(4)°, γ = 94.165(4)°. It exhibits a unique layered structure, the layers are parallel arrangement of the (0 0 1) plane and stack along the c-axis.

KeywordCa[b(C6h6o7)(2)](H2o)(4)Center Dot Hcl Crystal Structure Crystal Growth Inorganic-organic Borate
DOI10.1016/j.molstruc.2012.05.072
Indexed BySCI
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1604
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
Recommended Citation
GB/T 7714
Wu Hongping,Pan Shilie,Yu Hongwei,et al. Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl[J]. Journal of Molecular Structure,2012,1027(11):111-115.
APA Wu Hongping,Pan Shilie,Yu Hongwei,Huang Zhenjun,&Jia Dianzeng.(2012).Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl.Journal of Molecular Structure,1027(11),111-115.
MLA Wu Hongping,et al."Synthesis, structure and characterization of layered Ca[B(C6H6O7)(2)](H2O)(4)center dot HCl".Journal of Molecular Structure 1027.11(2012):111-115.
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