Synthesis, crystal structure and optical properties of Li2Cu5(PO4)(4)
Cui Liang; Pan Shilie; Han Jian; Dong Xiaoyu; Zhou Zhongxiang
2011
Source PublicationSolid State Sciences
ISSN1293-2558
Volume13Issue:6Pages:1304-1308
Abstract

The single crystals of Li2Cu5(PO4)(4) have been grown in the Li2CO3-H3BO3 borate fluxes. Li2Cu5(PO4)(4) crystallizes in the centrosymmetric triclinic space group P-1 with a = 6.03580(10) angstrom, b = 9.2211(2) angstrom, C = 11.4138(2) angstrom, alpha = 75.5750(10)degrees, beta = 80.2540(10)degrees, gamma = 74.1590(10)degrees, Z = 2. The three-dimensional framework is built up of LiO5, CuO4, Cu/LiO5 polyhedra and isolated PO4 tetrahedra. The IR spectrum and UV-Vis-NIR diffuse reflectance spectrum of Li2Cu5(PO4)(4) have been studied.

KeywordLithium Copper Phosphate Single Crystal Structure Three-dimensional Framework Ir Spectrum
Subject AreaChemistry ; Physics
DOI10.1016/j.solidstatesciences.2011.03.026
Indexed BySCI
WOS IDWOS:000292174000014
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1463
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Cui Liang,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of Li2Cu5(PO4)(4)[J]. Solid State Sciences,2011,13(6):1304-1308.
APA Cui Liang,Pan Shilie,Han Jian,Dong Xiaoyu,&Zhou Zhongxiang.(2011).Synthesis, crystal structure and optical properties of Li2Cu5(PO4)(4).Solid State Sciences,13(6),1304-1308.
MLA Cui Liang,et al."Synthesis, crystal structure and optical properties of Li2Cu5(PO4)(4)".Solid State Sciences 13.6(2011):1304-1308.
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