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学科主题: Chemistry ; Physics
题名: Synthesis, crystal structure and optical properties of Li2Cu5(PO4)(4)
作者: Cui Liang; Pan Shilie; Han Jian; Dong Xiaoyu; Zhou Zhongxiang
通讯作者: Pan, SL
关键词: Lithium copper phosphate ; Single crystal structure ; Three-dimensional framework ; IR spectrum
刊名: Solid State Sciences
发表日期: 2011
DOI: 10.1016/j.solidstatesciences.2011.03.026
卷: 13, 期:6, 页:1304-1308
收录类别: SCI
资助者: Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 200816120; Scientific Research Program of Urumqi of China G09212001
摘要: The single crystals of Li2Cu5(PO4)(4) have been grown in the Li2CO3-H3BO3 borate fluxes. Li2Cu5(PO4)(4) crystallizes in the centrosymmetric triclinic space group P-1 with a = 6.03580(10) angstrom, b = 9.2211(2) angstrom, C = 11.4138(2) angstrom, alpha = 75.5750(10)degrees, beta = 80.2540(10)degrees, gamma = 74.1590(10)degrees, Z = 2. The three-dimensional framework is built up of LiO5, CuO4, Cu/LiO5 polyhedra and isolated PO4 tetrahedra. The IR spectrum and UV-Vis-NIR diffuse reflectance spectrum of Li2Cu5(PO4)(4) have been studied.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1463
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Cui Liang,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of Li2Cu5(PO4)(4)[J]. Solid State Sciences,2011,13(6):1304-1308.
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文件名: Synthesis, crystal structure and optical properties of Li 2Cu 5(PO 4) 4.pdf
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