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学科主题: Chemistry
题名: Synthesis, structure and properties of Pb2Bi2AlB3O11
作者: Li Junjie; Pan Shilie; Zhao Wenwu; Tian Xuelin; Han Jian; Fan Xiaoyun
通讯作者: Pan, SL
关键词: Pb2Bi2AlB3O11 ; Borate ; Structure determination ; Single-crystal diffraction
刊名: Journal of Molecular Structure
发表日期: 2011
DOI: 10.1016/j.molstruc.2011.03.042
卷: 994, 期:1-3, 页:321-324
收录类别: SCI
摘要: Single crystals of Pb2Bi2AlB3O 11 were grown from a PbO/Bi2O3/Al 2O3/H3BO3/PbF2 flux. The single-crystal X-ray structural analysis showed that Pb2Bi 2AlB3O11 crystallizes in the monoclinic space group C2/c (No. 15) with a = 17.263(2) A˚, b = 8.7322(11) A˚, c = 6.8081(9) A˚, α = 90°, β = 90.566(2)°, γ = 90°, Z = 4 and R1 = 0.0393, wR2 = 0.1013. Its structure may be described as three-dimensional frameworks formed of (1 0 0) [Pb6Bi6Al3O6]∞ layers stacked along a-axis. The layers are interconnected via BO3 groups. The IR spectrum further confirmed the presence of BO3 groups in the structure. The thermal analysis suggests that Pb2Bi 2AlB3O11 is a congruently melting compound.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1454
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Li Junjie,Pan Shilie,Zhao Wenwu,et al. Synthesis, structure and properties of Pb2Bi2AlB3O11[J]. Journal of Molecular Structure,2011,994(1-3):321-324.
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