Synthesis, structure and properties of Pb2Bi2AlB3O11
Li Junjie; Pan Shilie; Zhao Wenwu; Tian Xuelin; Han Jian; Fan Xiaoyun
Source PublicationJournal of Molecular Structure

Single crystals of Pb2Bi2AlB3O11 were grown from a PbO/Bi2O3/Al2O3/H3BO3/PbF2 flux. The single-crystal X-ray structural analysis showed that Pb2Bi2AlB3O11 crystallizes in the monoclinic space group C2/c (No. 15) with a = 17.263(2) angstrom, b = 8.7322(11) angstrom, c=6.8081(9) angstrom, alpha =90 degrees, beta = 90.566(2)degrees, gamma =90 degrees, Z = 4 and R-1 = 0.0393, wR(2) = 0.1013. Its structure may be described as three-dimensional frameworks formed of (1 0 0) [Pb6Bi6Al3O6]infinity layers stacked along a-axis. The layers are interconnected via BO3 groups. The IR spectrum further confirmed the presence of BO3 groups in the structure. The thermal analysis suggests that Pb2Bi2AlB3O11 is a congruently melting compound.

KeywordPb2bi2alb3o11 Borate Structure Determination Single-crystal Diffraction
Subject AreaChemistry
Indexed BySCI
WOS IDWOS:000291085700046
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Li Junjie,Pan Shilie,Zhao Wenwu,et al. Synthesis, structure and properties of Pb2Bi2AlB3O11[J]. Journal of Molecular Structure,2011,994(1-3):321-324.
APA Li Junjie,Pan Shilie,Zhao Wenwu,Tian Xuelin,Han Jian,&Fan Xiaoyun.(2011).Synthesis, structure and properties of Pb2Bi2AlB3O11.Journal of Molecular Structure,994(1-3),321-324.
MLA Li Junjie,et al."Synthesis, structure and properties of Pb2Bi2AlB3O11".Journal of Molecular Structure 994.1-3(2011):321-324.
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