Synthesis, crystal structure and optical properties of the new lead fluoride borate-Pb2BO3F
Zhao Wenwu; Pan Shilie; Han Jian; Yao Jiyong; Yang Yun; Li Junjie; Zhang Min; Zhang Lian Han; Hang Yin
2011
Source PublicationJournal of Solid State Chemistry
ISSN0022-4596
Volume184Issue:11Pages:2849-2853
Abstract

A new compound, Pb2BO3F, has been grown by high temperature solution method from the PbO-PbF2-B2O3 system for the first time. The crystal structure of this compound has been identified by single crystal X-ray diffraction analysis. It crystallizes in the hexagonal system, space group P6(3)/m (No. 176) with unit-cell parameters a =7.2460(3) angstrom, c=14.5521(17) angstrom, Z=6, V=661.69(9) angstrom(3). Its structure was solved by the direct methods and refined to R-1=0.0163 and wR(2)=0.0367. The structure of Pb2BO3F consists of the distorted PbO3F2 groups and BO3 triangles, which are all symmetric with each other in the gestalt structure to the extent that the Pb2BO3F compound crystallizes in the symmetric space group. The powder X-ray diffraction pattern of the Pb2BO3F has been measured. The BO3 functional groups presented in the sample were identified by FTIR spectrum. The DTA curve of Pb2BO3F suggests that Pb2BO3F melts congruently at 448 degrees C.

KeywordPb2bo3f Synthesis Crystal Structure Borate
Subject AreaChemistry
DOI10.1016/j.jssc.2011.08.024
Indexed BySCI
WOS IDWOS:000296404200004
Citation statistics
Cited Times:28[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1444
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Tech Inst Phys & Chem, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China
Recommended Citation
GB/T 7714
Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of the new lead fluoride borate-Pb2BO3F[J]. Journal of Solid State Chemistry,2011,184(11):2849-2853.
APA Zhao Wenwu.,Pan Shilie.,Han Jian.,Yao Jiyong.,Yang Yun.,...&Hang Yin.(2011).Synthesis, crystal structure and optical properties of the new lead fluoride borate-Pb2BO3F.Journal of Solid State Chemistry,184(11),2849-2853.
MLA Zhao Wenwu,et al."Synthesis, crystal structure and optical properties of the new lead fluoride borate-Pb2BO3F".Journal of Solid State Chemistry 184.11(2011):2849-2853.
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