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学科主题: Chemistry
题名: Synthesis, crystal structure and optical properties of the new lead fluoride borate-Pb2BO3F
作者: Zhao Wenwu; Pan Shilie; Han Jian; Yao Jiyong; Yang Yun; Li Junjie; Zhang Min; Zhang Lian Han; Hang Yin
通讯作者: Pan, SL
关键词: Pb2BO3F ; Synthesis ; Crystal structure ; Borate
刊名: Journal of Solid State Chemistry
发表日期: 2011
DOI: 10.1016/j.jssc.2011.08.024
卷: 184, 期:11, 页:2849-2853
收录类别: SCI
资助者: Chinese Academy of Sciences KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; Key Laboratory of Electronic Information Materials and Devices of Xinjiang Uygur Autonomous Region of China xjys0901-2009-01; Scientific Research Program of Urumqi of China G09212001; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences
摘要: A new compound, Pb2BO3F, has been grown by high temperature solution method from the PbO-PbF2-B2O3 system for the first time. The crystal structure of this compound has been identified by single crystal X-ray diffraction analysis. It crystallizes in the hexagonal system, space group P6(3)/m (No. 176) with unit-cell parameters a =7.2460(3) angstrom, c=14.5521(17) angstrom, Z=6, V=661.69(9) angstrom(3). Its structure was solved by the direct methods and refined to R-1=0.0163 and wR(2)=0.0367. The structure of Pb2BO3F consists of the distorted PbO3F2 groups and BO3 triangles, which are all symmetric with each other in the gestalt structure to the extent that the Pb2BO3F compound crystallizes in the symmetric space group. The powder X-ray diffraction pattern of the Pb2BO3F has been measured. The BO3 functional groups presented in the sample were identified by FTIR spectrum. The DTA curve of Pb2BO3F suggests that Pb2BO3F melts congruently at 448 degrees C.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1444
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China;Tech Inst Phys & Chem, Beijing 100049, Peoples R China;Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China

Recommended Citation:
Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of the new lead fluoride borate-Pb2BO3F[J]. Journal of Solid State Chemistry,2011,184(11):2849-2853.
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