Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10
Yu Hongwei; Pan Shilie; Wu Hongping; Han Jian; Dong Xiaoyu; Zhou Zhongxiang; Pan, SL
2011
发表期刊Journal of Solid State Chemistry
ISSN224596
卷号184期号:7页码:1644-1648
摘要

A new ternary borate oxide, K3CdB5O10, has been synthesized by solid-state reaction at 580 degrees C. The compound crystallizes in the monoclinic space group P2(1)/n with a=7.6707 (7) angstrom, b=19.1765 (17) angstrom, c=7.8784 (6) angstrom, beta=115.6083 (49)degrees, and Z=4. The crystal structure consists of a two-dimensional infinite [CdB5O10] layer, which forms by connecting isolated double ring [B5O10] groups and CdO4 tetrahedra. K atoms filling in the interlayer and intralayer link the layers together and balance charge. The IR spectrum has been studied and confirmed the presence of both BO3 and BO4 groups, and the UV-vis-IR diffuse reflectance spectrum exhibits a band gap of about 3.4 eV. The DSC analysis proves that K3CdB5O10 is a congruent melting compound.

关键词K3cdb5o10 Pentaborate Synthesis Crystal Structure Optical Property
学科领域Chemistry
DOI10.1016/j.jssc.2011.05.007
收录类别SCI
WOS记录号WOS:000292718500010
引用统计
被引频次:28[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1443
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Yu Hongwei,Pan Shilie,Wu Hongping,et al. Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10[J]. Journal of Solid State Chemistry,2011,184(7):1644-1648.
APA Yu Hongwei.,Pan Shilie.,Wu Hongping.,Han Jian.,Dong Xiaoyu.,...&Pan, SL.(2011).Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10.Journal of Solid State Chemistry,184(7),1644-1648.
MLA Yu Hongwei,et al."Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10".Journal of Solid State Chemistry 184.7(2011):1644-1648.
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