中国科学院新疆理化技术研究所机构知识库
Advanced  
XJIPC OpenIR  > 新疆维吾尔自治区电子信息材料与器件重点实验室  > 期刊论文
学科主题: Chemistry
题名: Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10
作者: Yu Hongwei; Pan Shilie; Wu Hongping; Han Jian; Dong Xiaoyu; Zhou Zhongxiang
通讯作者: Pan, SL
关键词: K3CdB5O10 ; Pentaborate ; Synthesis ; Crystal structure ; Optical property
刊名: Journal of Solid State Chemistry
发表日期: 2011
DOI: 10.1016/j.jssc.2011.05.007
卷: 184, 期:7, 页:1644-1648
收录类别: SCI
摘要: A new ternary borate oxide, K3CdB5O10, has been synthesized by solid-state reaction at 580 °C. The compound crystallizes in the monoclinic space group P21/n with a=7.6707 (7) A˚, b=19.1765 (17) A˚, c=7.8784 (6) A˚, β=115.6083 (49)°, and Z=4. The crystal structure consists of a two-dimensional infinite [CdB5O10] layer, which forms by connecting isolated double ring [B5O10] groups and CdO4 tetrahedra. K atoms filling in the interlayer and intralayer link the layers together and balance charge. The IR spectrum has been studied and confirmed the presence of both BO3 and BO4 groups, and the UVvis-IR diffuse reflectance spectrum exhibits a band gap of about 3.4 eV. The DSC analysis proves that K3CdB5O10 is a congruent melting compound.
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1443
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

Files in This Item:
File Name/ File Size Content Type Version Access License
synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, k3cdb5o10.pdf(655KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Yu Hongwei,Pan Shilie,Wu Hongping,et al. Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10[J]. Journal of Solid State Chemistry,2011,184(7):1644-1648.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Yu Hongwei]'s Articles
[Pan Shilie]'s Articles
[Wu Hongping]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Yu Hongwei]‘s Articles
[Pan Shilie]‘s Articles
[Wu Hongping]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, k3cdb5o10.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace