Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H24
Luo Jiang; Pan Shilie; Li Hongyi; Zhou Zhongxiang; Yang Zhihua
2011
Source PublicationJournal of Materials Science
ISSN0022-2461
Volume46Issue:23Pages:7443-7448
Abstract

Single crystals of Rb2CaB8O26H24, a new noncentrosymmetric borate material, have been grown with sizes up to 8 9 5 9 3 mm(3) by the slow evaporation of water solution at room temperature. The structure of the compound was determined by single-crystal X-ray diffraction. It crystallizes in the orthorhombic system, space group P2(1)2(1)2(1) with a = 11.5288(3) angstrom, b = 12.6 334(4) angstrom, c = 16.6966(4) angstrom, Z = 4 and R-1 = 0.0405, wR(2) = 0.1043. Ultraviolet (UV)-vis spectrum transmission is performed on the Rb2CaB8O26H24, which shows an absorption edge about 195 nm in the UV region. Thermal properties were investigated by TG-DSC analysis. The powder second-harmonic generation (SHG) intensity measured by the Kurtz-Perry method indicates that Rb2CaB8O26H24 has about one-third of KDP (KH2PO4). The influence of different molar ratios and evaporation speed of water solution on crystal quality and size was also performed on the reported material.

Subject AreaMaterials Science
DOI10.1007/s10853-011-5710-6
Indexed BySCI
WOS IDWOS:000295179700012
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1439
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Luo Jiang,Pan Shilie,Li Hongyi,et al. Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H24[J]. Journal of Materials Science,2011,46(23):7443-7448.
APA Luo Jiang,Pan Shilie,Li Hongyi,Zhou Zhongxiang,&Yang Zhihua.(2011).Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H24.Journal of Materials Science,46(23),7443-7448.
MLA Luo Jiang,et al."Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H24".Journal of Materials Science 46.23(2011):7443-7448.
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