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学科主题: Materials Science
题名: New bidentate non-centrosymmetric borate-malate: Synthesis, structure and characterization of RbB(DL-C4H4O5)(2)center dot H2O
作者: Chen Zhaohui; Pan Shilie; Wu Hongping; Yang Yun; Fan Xiaoyun
通讯作者: Pan, SL
关键词: Optical materials ; Crystal growth ; Powder diffraction ; Crystal structure
刊名: Materials Chemistry and Physics
发表日期: 2011
DOI: 10.1016/j.matchemphys.2011.05.009
卷: 129, 期:1-2, 页:649-653
收录类别: SCI
摘要: A single crystal of RbB(dl-C4H4O5) 2·H2O (RBC) has been grown with a size of up to 11 mm × 8 mm × 3 mm through slow evaporation of its precursors' solution at room temperature. The structure of RBC was determined by single-crystal X-ray diffraction. Crystal data: RBC, Mr = 378.44; orthorhombic, space group Pna21 (No. 33); cell parameters, a = 11.4938(9) , b = 5.4021(5) , c = 21.1696(12) and Z = 4. It exhibits a two-dimensional layer structure down the b axis, consisting of RbO7 polyhedra, BO4 tetrahedra, malate groups, and H2O molecules. The material is second harmonic generation (SHG) active; its SHG intensity is about 2 times that of KH2PO4 (KDP).
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1437
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Xinjiang Univ, Phys & Chem Detecting Ctr, Urumqi 830046, Peoples R China

Recommended Citation:
Chen Zhaohui,Pan Shilie,Wu Hongping,et al. New bidentate non-centrosymmetric borate-malate: Synthesis, structure and characterization of RbB(DL-C4H4O5)(2)center dot H2O[J]. Materials Chemistry and Physics,2011,129(1-2):649-653.
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文件名: New bidentate non-centrosymmetric borate-malate Synthesis, structure and characterization of RbB(DL-C4H4O5)(2)center dot H2O.pdf
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