New bidentate non-centrosymmetric borate-malate: Synthesis, structure and characterization of RbB(DL-C4H4O5)(2)center dot H2O
Chen Zhaohui; Pan Shilie; Wu Hongping; Yang Yun; Fan Xiaoyun
2011
Source PublicationMaterials Chemistry and Physics
ISSN0254-0584
Volume129Issue:1-2Pages:649-653
Abstract

A single crystal of RbB(DL-C4H4O5)(2)center dot H2O (RBC) has been grown with a size of up to 11 mm x 8 mm x 3 mm through slow evaporation of its precursors' solution at room temperature. The structure of RBC was determined by single-crystal X-ray diffraction. Crystal data: RBC, M-r = 378.44; orthorhombic, space group Pna2(1) (No. 33); cell parameters, a = 11.4938(9) angstrom, b = 5.4021(5) angstrom, c = 21.1696(12) angstrom and Z = 4. It exhibits a two-dimensional layer structure down the b axis, consisting of RbO7 polyhedra, BO4 tetrahedra, malate groups, and H2O molecules. The material is second harmonic generation (SHG) active; its SHG intensity is about 2 times that of KH2PO4 (KDP).

KeywordOptical Materials Crystal Growth Powder Diffraction Crystal Structure
Subject AreaMaterials Science
DOI10.1016/j.matchemphys.2011.05.009
Indexed BySCI
WOS IDWOS:000292621200105
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1437
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
Affiliation1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Xinjiang Univ, Phys & Chem Detecting Ctr, Urumqi 830046, Peoples R China
Recommended Citation
GB/T 7714
Chen Zhaohui,Pan Shilie,Wu Hongping,et al. New bidentate non-centrosymmetric borate-malate: Synthesis, structure and characterization of RbB(DL-C4H4O5)(2)center dot H2O[J]. Materials Chemistry and Physics,2011,129(1-2):649-653.
APA Chen Zhaohui,Pan Shilie,Wu Hongping,Yang Yun,&Fan Xiaoyun.(2011).New bidentate non-centrosymmetric borate-malate: Synthesis, structure and characterization of RbB(DL-C4H4O5)(2)center dot H2O.Materials Chemistry and Physics,129(1-2),649-653.
MLA Chen Zhaohui,et al."New bidentate non-centrosymmetric borate-malate: Synthesis, structure and characterization of RbB(DL-C4H4O5)(2)center dot H2O".Materials Chemistry and Physics 129.1-2(2011):649-653.
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