Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9
Zhang Min; Pan Shilie; Han Jian; Zhou Zhongxiang
2011
Source PublicationJournal of Solid State Chemistry
ISSN0022-4596
Volume184Issue:4Pages:825-829
Abstract

A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) A˚, b=13.0234(2) A˚, c=8.5838(10) A˚, β=104.971(10)°, and Z=4. The crystal structure is composed of double ring [B5O 9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ∞[B5O 9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ∞[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB 5O9 were reported.

KeywordNapbb5o9 Borate Synthesis Crystal Structure
Subject AreaChemistry
DOI10.1016/j.jssc.2011.01.039
Indexed BySCI
WOS IDWOS:000289597100015
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Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1433
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhang Min,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9[J]. Journal of Solid State Chemistry,2011,184(4):825-829.
APA Zhang Min,Pan Shilie,Han Jian,&Zhou Zhongxiang.(2011).Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9.Journal of Solid State Chemistry,184(4),825-829.
MLA Zhang Min,et al."Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9".Journal of Solid State Chemistry 184.4(2011):825-829.
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