Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9
Zhang Min; Pan Shilie; Han Jian; Zhou Zhongxiang
2011
发表期刊Journal of Solid State Chemistry
ISSN0022-4596
卷号184期号:4页码:825-829
摘要

A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) A˚, b=13.0234(2) A˚, c=8.5838(10) A˚, β=104.971(10)°, and Z=4. The crystal structure is composed of double ring [B5O 9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ∞[B5O 9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ∞[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB 5O9 were reported.

关键词Napbb5o9 Borate Synthesis Crystal Structure
学科领域Chemistry
DOI10.1016/j.jssc.2011.01.039
收录类别SCI
WOS记录号WOS:000289597100015
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1433
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang Min,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9[J]. Journal of Solid State Chemistry,2011,184(4):825-829.
APA Zhang Min,Pan Shilie,Han Jian,&Zhou Zhongxiang.(2011).Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9.Journal of Solid State Chemistry,184(4),825-829.
MLA Zhang Min,et al."Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9".Journal of Solid State Chemistry 184.4(2011):825-829.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
synthesis, crystal s(759KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhang Min]的文章
[Pan Shilie]的文章
[Han Jian]的文章
百度学术
百度学术中相似的文章
[Zhang Min]的文章
[Pan Shilie]的文章
[Han Jian]的文章
必应学术
必应学术中相似的文章
[Zhang Min]的文章
[Pan Shilie]的文章
[Han Jian]的文章
相关权益政策
暂无数据
收藏/分享
文件名: synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, napbb5o9.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。