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学科主题: Chemistry
题名: Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9
作者: Zhang Min; Pan Shilie; Han Jian; Zhou Zhongxiang
通讯作者: Pan, SL
关键词: NaPbB5O9 ; Borate ; Synthesis ; Crystal structure
刊名: Journal of Solid State Chemistry
发表日期: 2011
卷: 184, 期:4, 页:825-829
收录类别: SCI
英文摘要: A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) A˚, b=13.0234(2) A˚, c=8.5838(10) A˚, β=104.971(10)°, and Z=4. The crystal structure is composed of double ring [B5O 9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ∞[B5O 9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ∞[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB 5O9 were reported.
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1433
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Zhang Min,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9[J]. Journal of Solid State Chemistry,2011,184(4):825-829.
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文件名: synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, napbb5o9.pdf
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