Synthesis of Environmentally Friendly Composite-Metal (Calcium and Magnesium) Oleate Detergent
Wang Yonglei; Eli Wumanjiang; Zhang Letao; Cai Guoxing; Eli, WMJ
2011
发表期刊INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN8885885
卷号50期号:3页码:1530-1535
摘要This article presents a method for synthesizing an environmentally friendly composite-metal (calcium and magnesium) oleate detergent, using oleic acid and composite alkaline salts (Ca(OH)(2) and active-60 MgO) with high activity and reactivity as raw materials. Reaction conditions, including the molar ratio of composite alkaline salts (Ca(OH)(2) and active-60 MgO) to oleic acid, the molar ratio of xylene to composite alkaline salts (Ca(OH)(2) and active-60 MgO), the molar ratio of methanol to composite alkaline salts (Ca(OH)(2) and active-60 MgO), the molar ratio of ammonia to composite alkaline salts (Ca(OH)(2) and active-60 MgO), the molar ratio of injected CO(2) to composite alkaline salts (Ca(OH)(2) and active-60 MgO), and CO(2) rate, were optimized. Using the optimized conditions, a high-alkali composite-metal (calcium and magnesium) oleate solution with a total base number (TBN) of 316 mg KOH/g and an overbased composite-metal (calcium and magnesium) oleate solution with a value of TBN = 412 mg KOH/g could be obtained. In addition, the relationship between the TBN of the product and the metal content (calcium and magnesium) also was discussed.
学科领域Engineering
DOI10.1021/ie101835v
WOS记录号WOS:000286499800038
引用统计
被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1431
专题新疆维吾尔自治区精细化工工程技术研究中心
通讯作者Eli, WMJ
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi Xinjiang 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Wang Yonglei,Eli Wumanjiang,Zhang Letao,et al. Synthesis of Environmentally Friendly Composite-Metal (Calcium and Magnesium) Oleate Detergent[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2011,50(3):1530-1535.
APA Wang Yonglei,Eli Wumanjiang,Zhang Letao,Cai Guoxing,&Eli, WMJ.(2011).Synthesis of Environmentally Friendly Composite-Metal (Calcium and Magnesium) Oleate Detergent.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,50(3),1530-1535.
MLA Wang Yonglei,et al."Synthesis of Environmentally Friendly Composite-Metal (Calcium and Magnesium) Oleate Detergent".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 50.3(2011):1530-1535.
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