Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12
Li Junjie; Pan Shilie; Zhao Wenwu; Tian Xuelin; Han Jian; Fan Xiaoyun
2011
Source PublicationSolid State Sciences
ISSN1293-2558
Volume13Issue:5Pages:966-969
Abstract

A novel boratotungstate, Pb6B2WO12, has been prepared by solid-state reaction. The single-crystal X-ray structural analysis showed that Pb6B2WO12 crystallizes in the orthorhombic space group Cmcm (No. 63) with a = 18.4904(5) , b = 6.35980(10) , c = 11.6789(2) , Z = 4 and R1 = 0.0253, wR2 = 0.0557. The compound is characterized by one-dimensional (Pb3O)∞1 chains formed by corner-sharing OPb4 tetrahedra. BO3 and WO4 groups are located around the chains to hold them together via Pb-O bonds. The IR spectra further confirmed the presence of BO3 groups in the structure. The thermal analysis suggests that Pb6B2WO 12 is a congruently melting compound.

KeywordPb6b2wo12 Boratotungstate Structure Determination Single-crystal Diffraction
Subject AreaChemistry ; Physics
DOI10.1016/j.solidstatesciences.2011.02.008
Indexed BySCI
WOS IDWOS:000291081900024
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1429
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Li Junjie,Pan Shilie,Zhao Wenwu,et al. Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12[J]. Solid State Sciences,2011,13(5):966-969.
APA Li Junjie,Pan Shilie,Zhao Wenwu,Tian Xuelin,Han Jian,&Fan Xiaoyun.(2011).Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12.Solid State Sciences,13(5),966-969.
MLA Li Junjie,et al."Synthesis and crystal structure of a novel boratotungstate: Pb6B2WO12".Solid State Sciences 13.5(2011):966-969.
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