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学科主题: Chemistry
题名: k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge
作者: Wu Hongping; Pan Shilie; Poeppelmeier Kenneth R.; Li Hongyi; Jia Dianzeng; Chen Zhaohui; Fan Xiaoyun; Yang Yun; Rondinelli James M.; Luo Haosu
通讯作者: Pan, SL
刊名: Journal of the American Chemical Society
发表日期: 2011
卷: 133, 期:20, 页:7786-7790
英文摘要: Introduction of the Cl- anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH 2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX 3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX 3.
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1425
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China;Northwestern Univ, Dept Chem, Evanston, IL 60208 USA;Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA;Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Shanghai 201800, Peoples R China

Recommended Citation:
Wu Hongping,Pan Shilie,Poeppelmeier Kenneth R.,et al. k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge[J]. Journal of the American Chemical Society,2011,133(20):7786-7790.
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