k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge
Wu Hongping; Pan Shilie; Poeppelmeier Kenneth R.; Li Hongyi; Jia Dianzeng; Chen Zhaohui; Fan Xiaoyun; Yang Yun; Rondinelli James M.; Luo Haosu
2011
Source PublicationJournal of the American Chemical Society
ISSN0002-7863
Volume133Issue:20Pages:7786-7790
Abstract

Introduction of the Cl- anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH 2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX 3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX 3.

Subject AreaChemistry
DOI10.1021/ja111083x
WOS IDWOS:000291580400034
Citation statistics
Cited Times:337[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1425
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
Affiliation1.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
2.Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
3.Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
4.Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA
5.Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Shanghai 201800, Peoples R China
Recommended Citation
GB/T 7714
Wu Hongping,Pan Shilie,Poeppelmeier Kenneth R.,et al. k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge[J]. Journal of the American Chemical Society,2011,133(20):7786-7790.
APA Wu Hongping.,Pan Shilie.,Poeppelmeier Kenneth R..,Li Hongyi.,Jia Dianzeng.,...&Luo Haosu.(2011).k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge.Journal of the American Chemical Society,133(20),7786-7790.
MLA Wu Hongping,et al."k3b6o10cl: a new structure analogous to perovskite with a large second harmonic generation response and deep uv absorption edge".Journal of the American Chemical Society 133.20(2011):7786-7790.
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