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Asymmetric Synthesis of cis-2-Aminocyclopropanols by Intramolecular Mannich Addition of Silyloxy Benzyl Carbanions
Liu Bo; Lu Chong-Dao; Lu, CD
2011
Source PublicationJournal of Organic Chemistry
ISSN223263
Volume76Issue:10Pages:4205-4209
AbstractAn efficient, highly diastereoselective method for the preparation of protected cis-2-aminocyclopropanols from N-tert-butanesulfinyl ketimines and various aryl acylsilanes is described. A tandem process for carbon-carbon bond formation via nucleophilic addition to acylsilanes, Brook rearrangement, and intramolecular Mannich reaction has been developed. © 2011 American Chemical Society.
Subject AreaChemistry
DOI10.1021/jo200585r
WOS IDWOS:000290465700073
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1423
Collection资源化学研究室
Corresponding AuthorLu, CD
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
Recommended Citation
GB/T 7714
Liu Bo,Lu Chong-Dao,Lu, CD. Asymmetric Synthesis of cis-2-Aminocyclopropanols by Intramolecular Mannich Addition of Silyloxy Benzyl Carbanions[J]. Journal of Organic Chemistry,2011,76(10):4205-4209.
APA Liu Bo,Lu Chong-Dao,&Lu, CD.(2011).Asymmetric Synthesis of cis-2-Aminocyclopropanols by Intramolecular Mannich Addition of Silyloxy Benzyl Carbanions.Journal of Organic Chemistry,76(10),4205-4209.
MLA Liu Bo,et al."Asymmetric Synthesis of cis-2-Aminocyclopropanols by Intramolecular Mannich Addition of Silyloxy Benzyl Carbanions".Journal of Organic Chemistry 76.10(2011):4205-4209.
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