中国科学院新疆理化技术研究所机构知识库
Advanced  
XJIPC OpenIR  > 新疆维吾尔自治区电子信息材料与器件重点实验室  > 期刊论文
学科主题: Materials Science
题名: growth, structure and properties of the non-centrosymmetric hydrated borate can2b8o26h32
作者: Li Hongyi; Pan Shilie; Wu Hongping; Yang Zhihua
通讯作者: Pan, SL
关键词: Optical materials ; Crystal growth ; Powder diffraction ; Crystal structure
刊名: Materials Chemistry and Physics
发表日期: 2011
卷: 129, 期:1-2, 页:176-179
收录类别: SCI
英文摘要: Nonlinear optical crystal of CaN2B8O 26H32 has been grown with sizes up to 9 × 8 × 5 mm3 by the solvent evaporation method. The structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction and IR spectrum analysis. CaN2B8O 26H32 crystallizes in the orthorhombic system, space group P212121, with unit-cell parameters a = 11.556(7) , b = 12.583(8) , c = 16.679(8) , Z = 4, V = 2425.2(2) 3, R1 = 0.0263, and wR2 = 0.0655. The structure is made up of CaO7 polyhedra, and [B4O5(OH) 4]2- polyborate anions, NH4+ cations, and H2O molecules. UV-vis-NIR diffuse reflectance spectrum is performed on the CaN2B8O26H32, which shows an absorption edge <190 nm in the UV region. Thermal properties were investigated by TG analyses. The powder second-harmonic generation intensity measured by the Kurtz-Perry method indicates that CaN 2B8O26H32 has about half times that of KH2PO4.
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1422
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

Files in This Item:
File Name/ File Size Content Type Version Access License
growth, structure and properties of the non-centrosymmetric hydrated borate can2b8o26h32.pdf(411KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Li Hongyi,Pan Shilie,Wu Hongping,et al. growth, structure and properties of the non-centrosymmetric hydrated borate can2b8o26h32[J]. Materials Chemistry and Physics,2011,129(1-2):176-179.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Li Hongyi]'s Articles
[Pan Shilie]'s Articles
[Wu Hongping]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Li Hongyi]‘s Articles
[Pan Shilie]‘s Articles
[Wu Hongping]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: growth, structure and properties of the non-centrosymmetric hydrated borate can2b8o26h32.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace