Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H32
Li Hongyi; Pan Shilie; Wu Hongping; Yang Zhihua
2011
发表期刊Materials Chemistry and Physics
ISSN0254-0584
卷号129期号:1-2页码:176-179
摘要

Nonlinear optical crystal of CaN2B8O 26H32 has been grown with sizes up to 9 × 8 × 5 mm3 by the solvent evaporation method. The structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction and IR spectrum analysis. CaN2B8O 26H32 crystallizes in the orthorhombic system, space group P212121, with unit-cell parameters a = 11.556(7) , b = 12.583(8) , c = 16.679(8) , Z = 4, V = 2425.2(2) 3, R1 = 0.0263, and wR2 = 0.0655. The structure is made up of CaO7 polyhedra, and [B4O5(OH) 4]2- polyborate anions, NH4+ cations, and H2O molecules. UV-vis-NIR diffuse reflectance spectrum is performed on the CaN2B8O26H32, which shows an absorption edge <190 nm in the UV region. Thermal properties were investigated by TG analyses. The powder second-harmonic generation intensity measured by the Kurtz-Perry method indicates that CaN 2B8O26H32 has about half times that of KH2PO4.

关键词Optical Materials Crystal Growth Powder Diffraction Crystal Structure
学科领域Materials Science
DOI10.1016/j.matchemphys.2011.03.068
收录类别SCI
WOS记录号WOS:000292621200029
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1422
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Li Hongyi,Pan Shilie,Wu Hongping,et al. Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H32[J]. Materials Chemistry and Physics,2011,129(1-2):176-179.
APA Li Hongyi,Pan Shilie,Wu Hongping,&Yang Zhihua.(2011).Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H32.Materials Chemistry and Physics,129(1-2),176-179.
MLA Li Hongyi,et al."Growth, structure and properties of the non-centrosymmetric hydrated borate CaN2B8O26H32".Materials Chemistry and Physics 129.1-2(2011):176-179.
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