A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks
Yang Yun; Pan Shilie; Han Jian; Hou Xueling; Zhou Zhongxiang; Zhao Wenwu; Chen Zhaohui; Zhang Min
2011
发表期刊CRYSTAL GROWTH & DESIGN
ISSN1528-7483
卷号11期号:9页码:3912-3916
摘要

A new noncentrosymmetric polyborate, Li6Rb5B 11O22, has been designed and synthesized in the Li 2O-Rb2O-B2O3 ternary system. The structure of the title compound was solved by single crystal X-ray diffraction analysis. It crystallizes in the monoclinic space group C2. The new structure contains an infinite three-dimensional matrix that is built from B 11O22 building blocks and LiOn (n = 4, 5), RbOn (n = 9, 10) polyhedra. The B11O22 building block has not been reported previously in any anhydrous and hydrated borates. The optical characterization of the compound indicates that its UV cutoff edge is below 190 nm. IR spectroscopy, thermal analysis, and second-harmonic generation were also performed on the reported material.

学科领域Chemistry ; Crystallography ; Materials Science
DOI10.1021/cg200471b
WOS记录号WOS:000294647600037
引用统计
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1413
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China;Coll Chem & Chem Engn, Beijing 100039, Peoples R China
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Yang Yun,Pan Shilie,Han Jian,et al. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks[J]. CRYSTAL GROWTH & DESIGN,2011,11(9):3912-3916.
APA Yang Yun.,Pan Shilie.,Han Jian.,Hou Xueling.,Zhou Zhongxiang.,...&Zhang Min.(2011).A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks.CRYSTAL GROWTH & DESIGN,11(9),3912-3916.
MLA Yang Yun,et al."A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks".CRYSTAL GROWTH & DESIGN 11.9(2011):3912-3916.
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