Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit
Zhang Min; Pan Shilie; Han Jian; Yang Zhihua; Su Xin; Zhao Wenwu; Pan, SL
2012
发表期刊Journal of Solid State Chemistry
ISSN224596
卷号190期号:6页码:92-97
摘要A novel ternary lithium strontium borate Li2Sr4B 12O23 crystal with size up to 20 mm×10 mm×4 mm has been grown via the top-seeded solution growth method below 730 °C. Single-crystal XRD analyses showed that Li2Sr4B 12O23 crystallizes in the monoclinic space group P2 1/c with a=6.4664(4) A˚, b=8.4878(4) A˚, c=15.3337(8) A˚, β=102.02(3)°, Z=2. The crystal structure is composed of [B10O18]6- network and isolated [B 2O5]4- unit. The IR spectrum further confirmed the presence of both BO3 and BO4 groups. TG-DSC and Transmission spectrum were reported. Band structures and density of states were calculated.
关键词Li2sr4b12o23 Crystal Structure Crystal Growth Borate
学科领域Chemistry
资助者Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211833; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143 ; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211833; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143 ; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211833; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143 ; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211833; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143
DOI10.1016/j.jssc.2012.01.061
收录类别SCI
资助者Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211833; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143 ; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211833; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143 ; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211833; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143 ; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211833; Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; "Western Light Joint Scholar Foundation" of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1402
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang Min,Pan Shilie,Han Jian,et al. Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit[J]. Journal of Solid State Chemistry,2012,190(6):92-97.
APA Zhang Min.,Pan Shilie.,Han Jian.,Yang Zhihua.,Su Xin.,...&Pan, SL.(2012).Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit.Journal of Solid State Chemistry,190(6),92-97.
MLA Zhang Min,et al."Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit".Journal of Solid State Chemistry 190.6(2012):92-97.
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