Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit
Zhang Min; Pan Shilie; Han Jian; Yang Zhihua; Su Xin; Zhao Wenwu
2012
发表期刊Journal of Solid State Chemistry
ISSN0022-4596
卷号190期号:6页码:92-97
摘要

A novel ternary lithium strontium borate Li2Sr4B 12O23 crystal with size up to 20 mm×10 mm×4 mm has been grown via the top-seeded solution growth method below 730 °C. Single-crystal XRD analyses showed that Li2Sr4B 12O23 crystallizes in the monoclinic space group P2 1/c with a=6.4664(4) A˚, b=8.4878(4) A˚, c=15.3337(8) A˚, β=102.02(3)°, Z=2. The crystal structure is composed of [B10O18]6- network and isolated [B 2O5]4- unit. The IR spectrum further confirmed the presence of both BO3 and BO4 groups. TG-DSC and Transmission spectrum were reported. Band structures and density of states were calculated.

关键词Li2sr4b12o23 Crystal Structure Crystal Growth Borate
学科领域Chemistry
DOI10.1016/j.jssc.2012.01.061
收录类别SCI
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1402
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhang Min,Pan Shilie,Han Jian,et al. Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit[J]. Journal of Solid State Chemistry,2012,190(6):92-97.
APA Zhang Min,Pan Shilie,Han Jian,Yang Zhihua,Su Xin,&Zhao Wenwu.(2012).Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit.Journal of Solid State Chemistry,190(6),92-97.
MLA Zhang Min,et al."Li2Sr4B12O23: A new alkali and alkaline-earth metal mixed borate with [B10O18](6-) network and isolated [B2O5](4-) unit".Journal of Solid State Chemistry 190.6(2012):92-97.
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