A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement
Yu Hongwei; Pan Shilie; Wu Hongping; Zhao Wenwu; Zhang Fangfang; Li Hongyi; Yang Zhihua; Pan, SL
2012
发表期刊JOURNAL OF MATERIALS CHEMISTRY
ISSN9599428
卷号22期号:5页码:2105-2110
摘要

Introduction of the stereo-effect of the lone pair of the Pb2+ cation in borate with layered-type arrangement of BO3 triangles generates a new phase-matching nonlinear optical material, Pb4O(BO3)(2). In the structure, the interesting Pb4O10 tetramers are connected to each other by sharing O atoms to form a 3D framework. In the space of the framework, the isolated BO3 and B2O5 groups are arranged parallel to the (100) to balance charge. The title compound melts congruently and exhibits a SHG response of similar to 3 times that of KDP and similar to 160 times that of a-SiO2. And it has a wide transparent region from the UV to near IR region with a UV cut-off edge of 280 nm, which means that Pb4O(BO3)(2) is a very promising NLO material for potential application.

学科领域Chemistry ; Materials Science
DOI10.1039/c1jm14590h
收录类别SCI
WOS记录号WOS:000298970700054
引用统计
被引频次:85[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1400
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan, SL
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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Yu Hongwei,Pan Shilie,Wu Hongping,et al. A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(5):2105-2110.
APA Yu Hongwei.,Pan Shilie.,Wu Hongping.,Zhao Wenwu.,Zhang Fangfang.,...&Pan, SL.(2012).A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement.JOURNAL OF MATERIALS CHEMISTRY,22(5),2105-2110.
MLA Yu Hongwei,et al."A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement".JOURNAL OF MATERIALS CHEMISTRY 22.5(2012):2105-2110.
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