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学科主题: Chemistry ; Materials Science
题名: A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement
作者: Yu Hongwei; Pan Shilie; Wu Hongping; Zhao Wenwu; Zhang Fangfang; Li Hongyi; Yang Zhihua
通讯作者: Pan, SL
刊名: JOURNAL OF MATERIALS CHEMISTRY
发表日期: 2012
DOI: 10.1039/c1jm14590h
卷: 22, 期:5, 页:2105-2110
收录类别: SCI
资助者: Chinese Academy of Sciences KJCX2-EW-209-3, KJCX2-EW-H03-03; National Natural Science Foundation of China 50802110, 21001114; Chinese Academy of Sciences; Western Light Joint Scholar Foundation of Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201116143
摘要: Introduction of the stereo-effect of the lone pair of the Pb2+ cation in borate with layered-type arrangement of BO3 triangles generates a new phase-matching nonlinear optical material, Pb 4O(BO3)2. In the structure, the interesting Pb4O10 tetramers are connected to each other by sharing O atoms to form a 3D framework. In the space of the framework, the isolated BO3 and B2O5 groups are arranged parallel to the (100) to balance charge. The title compound melts congruently and exhibits a SHG response of ∼3 times that of KDP and ∼160 times that of a-SiO 2. And it has a wide transparent region from the UV to near IR region with a UV cut-off edge of 280 nm, which means that Pb4O(BO 3)2 is a very promising NLO material for potential application.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1400
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Yu Hongwei,Pan Shilie,Wu Hongping,et al. A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(5):2105-2110.
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