A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement
Yu Hongwei; Pan Shilie; Wu Hongping; Zhao Wenwu; Zhang Fangfang; Li Hongyi; Yang Zhihua
2012
Source PublicationJOURNAL OF MATERIALS CHEMISTRY
ISSN0959-9428
Volume22Issue:5Pages:2105-2110
Abstract

Introduction of the stereo-effect of the lone pair of the Pb2+ cation in borate with layered-type arrangement of BO3 triangles generates a new phase-matching nonlinear optical material, Pb4O(BO3)(2). In the structure, the interesting Pb4O10 tetramers are connected to each other by sharing O atoms to form a 3D framework. In the space of the framework, the isolated BO3 and B2O5 groups are arranged parallel to the (100) to balance charge. The title compound melts congruently and exhibits a SHG response of similar to 3 times that of KDP and similar to 160 times that of a-SiO2. And it has a wide transparent region from the UV to near IR region with a UV cut-off edge of 280 nm, which means that Pb4O(BO3)(2) is a very promising NLO material for potential application.

Subject AreaChemistry ; Materials Science
DOI10.1039/c1jm14590h
Indexed BySCI
WOS IDWOS:000298970700054
Citation statistics
Cited Times:90[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1400
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Yu Hongwei,Pan Shilie,Wu Hongping,et al. A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(5):2105-2110.
APA Yu Hongwei.,Pan Shilie.,Wu Hongping.,Zhao Wenwu.,Zhang Fangfang.,...&Yang Zhihua.(2012).A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement.JOURNAL OF MATERIALS CHEMISTRY,22(5),2105-2110.
MLA Yu Hongwei,et al."A new congruent-melting oxyborate, Pb4O(BO3)(2) with optimally aligned BO3 triangles adopting layered-type arrangement".JOURNAL OF MATERIALS CHEMISTRY 22.5(2012):2105-2110.
Files in This Item:
File Name/Size DocType Version Access License
a new congruent-melt(474KB)期刊论文作者接受稿开放获取CC BY-NC-SAView Application Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yu Hongwei]'s Articles
[Pan Shilie]'s Articles
[Wu Hongping]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yu Hongwei]'s Articles
[Pan Shilie]'s Articles
[Wu Hongping]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yu Hongwei]'s Articles
[Pan Shilie]'s Articles
[Wu Hongping]'s Articles
Terms of Use
No data!
Social Bookmark/Share
File name: a new congruent-melting oxyborate, pb4o(bo3) 2 with optimally aligned bo3 triangles adopting layered-type arrangement.pdf
Format: Adobe PDF
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.