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Free-standing poly[poly(N-vinyl carbazole)]-supported Pt-based catalysts with enhanced performance for methanol electro-oxidation in alkaline medium
Jiang Fengxing; Ren Fangfang; Zhou Weiqiang; Du Yukou; Xu Jingkun; Yang Ping; Wang Chuanyi
2012
发表期刊Fuel
ISSN162361
卷号102期号:12页码:560-566
摘要Pt-based catalysts with free-standing poly[poly(N-vinyl carbazole)] (PPVK) as support (PtM/PPVK, M = Pd, Au, and Ru) on a glassy carbon electrode (GCE) have been successfully prepared by an electrochemical method. Cyclic voltammetric and chronoamperometric methods are used to investigate the electrocatalytic activity and stability of as-prepared catalysts. It is found that PPVK film as support effectively enhances the catalytic acitivity of Pt nanoparticles for methanol electro-oxidation in alkaline medium. The bimetallic PtM nanoparticles obtained potentiostatically on the PPVK film show the higher electrocatalytic activity than bare Pt/GCE and JM Pt/C. In addition, to pin down the external influencing factors, systematic studies have been conducted on the methanol electro-oxidation at as-prepared catalysts as a function of platinum loading, PPVK mass, methanol and KOH concentrations. © 2012 Elsevier Ltd. All rights reserved.
关键词Free-standing Film Pt-based Catalysts Methanol Electro-oxidation Alkaline Medium
学科领域Energy & Fuels ; Engineering
DOI10.1016/j.fuel.2012.07.008
收录类别SCI
WOS记录号WOS:000308804500067
引用统计
被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1395
专题环境科学与技术研究室
作者单位Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China;Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
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Jiang Fengxing,Ren Fangfang,Zhou Weiqiang,et al. Free-standing poly[poly(N-vinyl carbazole)]-supported Pt-based catalysts with enhanced performance for methanol electro-oxidation in alkaline medium[J]. Fuel,2012,102(12):560-566.
APA Jiang Fengxing.,Ren Fangfang.,Zhou Weiqiang.,Du Yukou.,Xu Jingkun.,...&Wang Chuanyi.(2012).Free-standing poly[poly(N-vinyl carbazole)]-supported Pt-based catalysts with enhanced performance for methanol electro-oxidation in alkaline medium.Fuel,102(12),560-566.
MLA Jiang Fengxing,et al."Free-standing poly[poly(N-vinyl carbazole)]-supported Pt-based catalysts with enhanced performance for methanol electro-oxidation in alkaline medium".Fuel 102.12(2012):560-566.
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