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Effect of lithium boron oxide glass coating on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2
Dou Junqing; Kang Xueya; Wumaier Tuerdi; Yu Hongwei; Hua Ning; Han Ying; Xu Guoqing; Kang, XY
2012
发表期刊Journal of Solid State Electrochemistry
ISSN14328488
卷号16期号:4页码:1481-1486
摘要The effect of the lithium boron oxide glass coating on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2 has been investigated via solution method. The morphology, structure, and electrochemical properties of the bare and coated LiNi1/3Co 1/3Mn1/3O2 are characterized by scanning electron microscopy, X-ray diffraction, electrochemical impedance spectroscopy, and charge-discharge tests. The results showed that the lattice structure of LiNi1/3Co1/3Mn1/3O2 is not changed after coating. The coating sample shows good high-rate discharge performance (148 mAh g-1 at 5.0 C rate) and cycling stability even at high temperature (with the capacities retention about 99% and 87% at room and elevated temperature after 50 cycles). The Li+ diffusion coefficient is also largely improved, while the charge transfer resistance, side reactions within cell, and the erosion of Hydrofluoric Acid all reduced. Consequently, the good electrochemical performances are obtained.
关键词Lithium Boron Oxide Glass Coating Cathode Material Lithium-ion Batteries
学科领域Electrochemistry
DOI10.1007/s10008-011-1550-1
收录类别SCI
WOS记录号WOS:000301983300021
引用统计
被引频次:19[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1393
专题材料物理与化学研究室
通讯作者Kang, XY
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Xinjiang, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Xinjiang Key Labs Elect Informat Mat & Devices, Urumqi 830011, Xinjiang, Peoples R China
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GB/T 7714
Dou Junqing,Kang Xueya,Wumaier Tuerdi,et al. Effect of lithium boron oxide glass coating on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2[J]. Journal of Solid State Electrochemistry,2012,16(4):1481-1486.
APA Dou Junqing.,Kang Xueya.,Wumaier Tuerdi.,Yu Hongwei.,Hua Ning.,...&Kang, XY.(2012).Effect of lithium boron oxide glass coating on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2.Journal of Solid State Electrochemistry,16(4),1481-1486.
MLA Dou Junqing,et al."Effect of lithium boron oxide glass coating on the electrochemical performance of LiNi1/3Co1/3Mn1/3O2".Journal of Solid State Electrochemistry 16.4(2012):1481-1486.
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