Further Examples of the P-O-P Connection in Borophosphates: Synthesis and Characterization of Li2Cs2B2P4O15, LiK2BP2O8, and Li3M2BP4O14 (M=K, Rb)
Wang Ying; Pan Shilie; Shi Yunjing; Pan, SL
2012
Source PublicationChemistry - A European Journal
ISSN9476539
Volume18Issue:38Pages:12046-12051
AbstractA new series of anhydrous mixed alkali-metal borophosphates-Li 2Cs2B2P4O15 (1), LiK 2BP2O8 (2), Li3K2BP 4O14 (3), and Li3Rb2BP 4O14 (4)-have been successfully synthesized by using the conventional solid-state reaction method. Compound 1 contains a novel fundamental building unit (FBU), [B4P8O30], with B/P=1:2. Compound 2 contains an FBU of [B2P4O 16] with B/P=1:2. Compounds 3 and 4 are isotypic, and they have a [B(P2O7)2] unit as their FBU. In all four compounds, their FBUs are connected through corner sharing to generate layered anionic partial structures, and then further linked with metallic polyhedra to form three-dimensional (3D) frameworks. Most interestingly, three of the four compounds contain direct P-O-P connections in their structures, which is extremely rare among borophosphates. Thermal analyses, IR spectroscopy, and UV/Vis/near-IR diffuse reflectance spectroscopy have also been performed on the four title compounds.
KeywordAlkali Metals Borophosphates Crystal Growth Solid-state Reactions Structure Elucidation
Subject AreaChemistry
Funding OrganizationNational Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143 ; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143 ; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143 ; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143
DOI10.1002/chem.201201356
Indexed BySCI
Funding OrganizationNational Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143 ; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143 ; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143 ; National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143
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Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1392
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
Corresponding AuthorPan, SL
AffiliationChinese Acad Sci, Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Wang Ying,Pan Shilie,Shi Yunjing,et al. Further Examples of the P-O-P Connection in Borophosphates: Synthesis and Characterization of Li2Cs2B2P4O15, LiK2BP2O8, and Li3M2BP4O14 (M=K, Rb)[J]. Chemistry - A European Journal,2012,18(38):12046-12051.
APA Wang Ying,Pan Shilie,Shi Yunjing,&Pan, SL.(2012).Further Examples of the P-O-P Connection in Borophosphates: Synthesis and Characterization of Li2Cs2B2P4O15, LiK2BP2O8, and Li3M2BP4O14 (M=K, Rb).Chemistry - A European Journal,18(38),12046-12051.
MLA Wang Ying,et al."Further Examples of the P-O-P Connection in Borophosphates: Synthesis and Characterization of Li2Cs2B2P4O15, LiK2BP2O8, and Li3M2BP4O14 (M=K, Rb)".Chemistry - A European Journal 18.38(2012):12046-12051.
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