中国科学院新疆理化技术研究所机构知识库
Advanced  
XJIPC OpenIR  > 新疆维吾尔自治区电子信息材料与器件重点实验室  > 期刊论文
学科主题: Chemistry
题名: Further Examples of the P-O-P Connection in Borophosphates: Synthesis and Characterization of Li2Cs2B2P4O15, LiK2BP2O8, and Li3M2BP4O14 (M=K, Rb)
作者: Wang Ying; Pan Shilie; Shi Yunjing
通讯作者: Pan, SL
关键词: alkali metals ; borophosphates ; crystal growth ; solid-state reactions ; structure elucidation
刊名: Chemistry - A European Journal
发表日期: 2012
DOI: 10.1002/chem.201201356
卷: 18, 期:38, 页:12046-12051
收录类别: SCI
资助者: National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of the Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of the Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143
摘要: A new series of anhydrous mixed alkali-metal borophosphates-Li 2Cs2B2P4O15 (1), LiK 2BP2O8 (2), Li3K2BP 4O14 (3), and Li3Rb2BP 4O14 (4)-have been successfully synthesized by using the conventional solid-state reaction method. Compound 1 contains a novel fundamental building unit (FBU), [B4P8O30], with B/P=1:2. Compound 2 contains an FBU of [B2P4O 16] with B/P=1:2. Compounds 3 and 4 are isotypic, and they have a [B(P2O7)2] unit as their FBU. In all four compounds, their FBUs are connected through corner sharing to generate layered anionic partial structures, and then further linked with metallic polyhedra to form three-dimensional (3D) frameworks. Most interestingly, three of the four compounds contain direct P-O-P connections in their structures, which is extremely rare among borophosphates. Thermal analyses, IR spectroscopy, and UV/Vis/near-IR diffuse reflectance spectroscopy have also been performed on the four title compounds.
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1392
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

Files in This Item:
File Name/ File Size Content Type Version Access License
Further Examples of the P-O-P Connection in Borophosphates Synthesis.pdf(774KB)期刊论文作者接受稿开放获取View 联系获取全文

作者单位: Chinese Acad Sci, Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

Recommended Citation:
Wang Ying,Pan Shilie,Shi Yunjing. Further Examples of the P-O-P Connection in Borophosphates: Synthesis and Characterization of Li2Cs2B2P4O15, LiK2BP2O8, and Li3M2BP4O14 (M=K, Rb)[J]. Chemistry - A European Journal,2012,18(38):12046-12051.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Wang Ying]'s Articles
[Pan Shilie]'s Articles
[Shi Yunjing]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Wang Ying]‘s Articles
[Pan Shilie]‘s Articles
[Shi Yunjing]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: Further Examples of the P-O-P Connection in Borophosphates Synthesis.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace