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学科主题: Chemistry ; Physics
题名: synthesis, crystal structure and characterization of a new compound, li3nabab6o12
作者: Chen Songjie; Pan Shilie; Zhao Wenwu; Yang Zhihua; Wu Hongping; Yang Yun
通讯作者: Pan, SL
关键词: Li3NaBaB6O12 ; Crystal structure ; IR spectrum ; UV-vis-NIR diffuse-reflectance spectrum ; Band structures
刊名: Solid State Sciences
发表日期: 2012
DOI: 10.1016/j.solidstatesciences.2012.05.026
卷: 14, 期:8, 页:1186-1190
收录类别: SCI
摘要: Li3NaBaB6O12 was synthesized by high temperature solution method. It crystallizes in trigonal space group R3 (No. 148) with lattice constants a = 9.462(9) A˚, c = 18.71(3) A˚, Z = 6. The crystal structure of Li3NaBaB6O12 is a three-dimensional (3D) network composed of the isolated twelve-membered cyclic B12O24 groups interconnected by NaO6, LiO 4 and BaO9 polyhedra. Functional groups in the sample were identified by IR spectrum. Li3NaBaB6O12 exhibits a short UV cutoff edge below 190 nm. Band structures and density of states were calculated.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1384
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Chen Songjie,Pan Shilie,Zhao Wenwu,et al. synthesis, crystal structure and characterization of a new compound, li3nabab6o12[J]. Solid State Sciences,2012,14(8):1186-1190.
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文件名: synthesis, crystal structure and characterization of a new compound, li3nabab6o12.pdf
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