synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10
Wu Hongping; Pan Shilie; Yu Hongwei; Chen Zhaohui; Zhang Fangfang
2012
Source PublicationSolid State Sciences
ISSN1293-2558
Volume14Issue:7Pages:936-940
Abstract

A new compound. K3ZnB5O10, has been synthesized by solid-state reaction. It crystallizes in the monoclinic system, space group P2(1)/n with unit-cell parameters a = 7.6391(5) angstrom, b = 19.2304(13) angstrom, c = 7.6905(5) angstrom beta = 116.698(4)degrees and Z = 4. The structure of the compound is solved by the direct methods and refined to R1 = 0.0286 and wR2 = 0.0600. K3ZnB5O10 contains a two-dimensional ZnB5O10 layer, which forms by connecting isolated double ring [B5O10] groups and ZnO4 tetrahedra. The K atoms filling in the interlayer and intralayer link the layers together. Functional groups presented in the sample were identified by FTIR spectrum. UV-vis-NIR diffuse reflectance spectrum exhibits ultraviolet cutoff edge is about 190 nm. The DSC analysis proves that K3ZnB5O10 is a congruently melting compound.

KeywordK3znb5o10 Single Crystal Growth X-ray Diffraction Optical Properties
Subject AreaChemistry ; Physics
DOI10.1016/j.solidstatesciences.2012.04.035
Indexed BySCI
WOS IDWOS:000307032500029
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1382
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China; Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China
Recommended Citation
GB/T 7714
Wu Hongping,Pan Shilie,Yu Hongwei,et al. synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10[J]. Solid State Sciences,2012,14(7):936-940.
APA Wu Hongping,Pan Shilie,Yu Hongwei,Chen Zhaohui,&Zhang Fangfang.(2012).synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10.Solid State Sciences,14(7),936-940.
MLA Wu Hongping,et al."synthesis, crystal structure and properties of a new congruently melting compound, k3znb5o10".Solid State Sciences 14.7(2012):936-940.
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