Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10

doi:10.1016/j.molstruc.2012.04.034

	Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10
	Chen Songjie; Pan Shilie; Wu Hongping; Han Jian; Zhang Min; Zhang Fangfang
	2012
发表期刊	Journal of Molecular Structure
ISSN	0022-2860
卷号	1021 期号:4 页码:118-122
摘要	A new phase of the compound, Na3ZnB5O10, crystallizes in orthorhombic space group Pbca (No. 61) with lattice constants a = 7.8923(4) angstrom, b = 12.2437(7) angstrom, c = 18.0636(11) angstrom, Z = 8. The Na3ZnB5O10 structure exhibits that the isolated B5O10 groups are bridged by ZnO4 tetrahedra and NaOn (n = 5,7) polyhedra through the vertex oxygen atoms to form an infinite three-dimensional structure. Functional groups in the sample were identified by IR spectrum. Na3ZnB5O10 has a phase transition, and exhibits a short-wavelength absorption onset below 190 nm.
关键词	Na3znb5o10 Powder Synthesis Crystal Structure Uv-vis-nir Diffuse-reflectance Spectrum Tg-dsc Curve
学科领域	Chemistry
DOI	10.1016/j.molstruc.2012.04.034
收录类别	SCI
WOS记录号	WOS:000307200900017
引用统计	被引频次：8[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.xjipc.cas.cn/handle/365002/1381
专题	新疆维吾尔自治区电子信息材料与器件重点实验室材料物理与化学研究室
通讯作者	Pan Shilie
作者单位	Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Chen Songjie,Pan Shilie,Wu Hongping,et al. Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10[J]. Journal of Molecular Structure,2012,1021(4):118-122.
APA	Chen Songjie,Pan Shilie,Wu Hongping,Han Jian,Zhang Min,&Zhang Fangfang.(2012).Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10.Journal of Molecular Structure,1021(4),118-122.
MLA	Chen Songjie,et al."Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10".Journal of Molecular Structure 1021.4(2012):118-122.

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