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学科主题: Chemistry
题名: Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10
作者: Chen Songjie; Pan Shilie; Wu Hongping; Han Jian; Zhang Min; Zhang Fangfang
通讯作者: Pan, SL
关键词: Na3ZnB5O10 ; Powder synthesis ; Crystal structure ; UV-Vis-NIR diffuse-reflectance spectrum ; TG-DSC curve
刊名: Journal of Molecular Structure
发表日期: 2012
DOI: 10.1016/j.molstruc.2012.04.034
卷: 1021, 期:4, 页:118-122
收录类别: SCI
摘要: A new phase of the compound, Na3ZnB5O10, crystallizes in orthorhombic space group Pbca (No. 61) with lattice constants a = 7.8923(4) A˚, b = 12.2437(7) A˚, c = 18.0636(11) A˚, Z = 8. The Na3ZnB5O10 structure exhibits that the isolated B5O10 groups are bridged by ZnO4 tetrahedra and NaOn (n = 5, 7) polyhedra through the vertex oxygen atoms to form an infinite three-dimensional structure. Functional groups in the sample were identified by IR spectrum. Na3ZnB5O 10 has a phase transition, and exhibits a short-wavelength absorption onset below 190 nm.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1381
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

Recommended Citation:
Chen Songjie,Pan Shilie,Wu Hongping,et al. Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10[J]. Journal of Molecular Structure,2012,1021(4):118-122.
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文件名: synthesis, crystal structure and optical properties of a new orthorhombic phase, na3znb5o10.pdf
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