Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10
Chen Songjie; Pan Shilie; Wu Hongping; Han Jian; Zhang Min; Zhang Fangfang
2012
发表期刊Journal of Molecular Structure
ISSN0022-2860
卷号1021期号:4页码:118-122
摘要

A new phase of the compound, Na3ZnB5O10, crystallizes in orthorhombic space group Pbca (No. 61) with lattice constants a = 7.8923(4) angstrom, b = 12.2437(7) angstrom, c = 18.0636(11) angstrom, Z = 8. The Na3ZnB5O10 structure exhibits that the isolated B5O10 groups are bridged by ZnO4 tetrahedra and NaOn (n = 5,7) polyhedra through the vertex oxygen atoms to form an infinite three-dimensional structure. Functional groups in the sample were identified by IR spectrum. Na3ZnB5O10 has a phase transition, and exhibits a short-wavelength absorption onset below 190 nm.

关键词Na3znb5o10 Powder Synthesis Crystal Structure Uv-vis-nir Diffuse-reflectance Spectrum Tg-dsc Curve
学科领域Chemistry
DOI10.1016/j.molstruc.2012.04.034
收录类别SCI
WOS记录号WOS:000307200900017
引用统计
被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1381
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Chen Songjie,Pan Shilie,Wu Hongping,et al. Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10[J]. Journal of Molecular Structure,2012,1021(4):118-122.
APA Chen Songjie,Pan Shilie,Wu Hongping,Han Jian,Zhang Min,&Zhang Fangfang.(2012).Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10.Journal of Molecular Structure,1021(4),118-122.
MLA Chen Songjie,et al."Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10".Journal of Molecular Structure 1021.4(2012):118-122.
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