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题名: Structure, growth and properties of a novel polar material, KSr4B3O9
作者: Zhao Wenwu; Pan Shilie; Wang Yongjiang; Yang Zhihua; Wang Xian; Han Jian
通讯作者: Pan, SL
关键词: Polar material ; Structure ; Growth ; Optical properties ; Theoretical calculation
刊名: Journal of Solid State Chemistry
发表日期: 2012
DOI: 10.1016/j.jssc.2012.01.008
卷: 195, 期:11, 页:73-78
收录类别: SCI
资助者: National Natural Science Foundation of China U1129301, 51172277, 50802110, 21101167, 21101168, 11104344; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; Chinese Academy of Sciences; Xinjiang Uygur Autonomous Region of China 201130111; "High Technology Research and Development Program" of Xinjiang Uygur Autonomous Region of China 201116143
摘要: A novel polar material, KSr4B3O9, has been obtained by the high temperature solution method for the first time. It crystallizes in the polar space group Ama2. The material exhibits a three-dimensional structure consisting of interconnecting KO10 groups, SrOx (x=8, 9) units and isolated BO3 triangles. DSC/TG curve shows that KSr4B3O9 melts incongruently. The calculated band structures and the density of states of KSr4B3O9 suggest that its direct gap is 3.897 eV. The absorption spectrum indicates the absorption edge of KSr 4B3O9 is about 302 nm. It produces SHG intensity about as large as that of KH2PO4 (KDP) and is phase matchable.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1378
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China;Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion SINANO, Beijing, Peoples R China

Recommended Citation:
Zhao Wenwu,Pan Shilie,Wang Yongjiang,et al. Structure, growth and properties of a novel polar material, KSr4B3O9[J]. Journal of Solid State Chemistry,2012,195(11):73-78.
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文件名: structure, growth and properties of a novel polar material, ksr 4b3o9.pdf
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