Structure, growth and properties of a novel polar material, KSr4B3O9
Zhao Wenwu; Pan Shilie; Wang Yongjiang; Yang Zhihua; Wang Xian; Han Jian
2012
Source PublicationJournal of Solid State Chemistry
ISSN0022-4596
Volume195Issue:11Pages:73-78
Abstract

A novel polar material, KSr4B3O9, has been obtained by the high temperature solution method for the first time. It crystallizes in the polar space group Ama2. The material exhibits a three-dimensional structure consisting of interconnecting KO10 groups, SrOx (x=8, 9) units and isolated BO3 triangles. DSC/TG curve shows that KSr4B3O9 melts incongruently. The calculated band structures and the density of states of KSr4B3O9 suggest that its direct gap is 3.897 eV. The absorption spectrum indicates the absorption edge of KSr 4B3O9 is about 302 nm. It produces SHG intensity about as large as that of KH2PO4 (KDP) and is phase matchable.

KeywordPolar Material Structure Growth Optical Properties Theoretical Calculation
Funding OrganizationNational Natural Science Foundation of China U1129301, 51172277, 50802110, 21101167, 21101168, 11104344 ; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03 ; Chinese Academy of Sciences ; Xinjiang Uygur Autonomous Region of China 201130111 ; National Natural Science Foundation of China U1129301, 51172277, 50802110, 21101167, 21101168, 11104344 ; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03 ; Chinese Academy of Sciences ; Xinjiang Uygur Autonomous Region of China 201130111
DOI10.1016/j.jssc.2012.01.008
Indexed BySCI
Funding OrganizationNational Natural Science Foundation of China U1129301, 51172277, 50802110, 21101167, 21101168, 11104344 ; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03 ; Chinese Academy of Sciences ; Xinjiang Uygur Autonomous Region of China 201130111 ; National Natural Science Foundation of China U1129301, 51172277, 50802110, 21101167, 21101168, 11104344 ; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03 ; Chinese Academy of Sciences ; Xinjiang Uygur Autonomous Region of China 201130111
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Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1378
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
Affiliation1.Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion SINANO, Beijing, Peoples R China
Recommended Citation
GB/T 7714
Zhao Wenwu,Pan Shilie,Wang Yongjiang,et al. Structure, growth and properties of a novel polar material, KSr4B3O9[J]. Journal of Solid State Chemistry,2012,195(11):73-78.
APA Zhao Wenwu,Pan Shilie,Wang Yongjiang,Yang Zhihua,Wang Xian,&Han Jian.(2012).Structure, growth and properties of a novel polar material, KSr4B3O9.Journal of Solid State Chemistry,195(11),73-78.
MLA Zhao Wenwu,et al."Structure, growth and properties of a novel polar material, KSr4B3O9".Journal of Solid State Chemistry 195.11(2012):73-78.
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