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学科主题: Chemistry
题名: A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12
作者: Chen Songjie; Pan Shilie; Zhao Wenwu; Yu Hongwei; Wu Hongping; Yang Zhihua; Yang Yun
通讯作者: Pan, SL
刊名: Dalton Transactions
发表日期: 2012
DOI: 10.1039/c2dt30608e
卷: 41, 期:30, 页:9202-9208
收录类别: SCI
摘要: A new noncentrosymmetric vanadoborate compound, K2SrVB 5O12, is synthesized by the high temperature solution method. It crystallizes in the monoclinic space group P21 (no. 4) with lattice constants a = 6.618(3) A˚, b = 8.378(4) A˚, c = 9.974(5) A˚, β = 99.789(6)°, Z = 2. The structure consists of vanadoborate anionic layers with K+ and Sr2+ cations filling the void spaces via electrostatic interactions to form the three-dimensional network. The TG-DSC curves and the UV-Vis-NIR diffuse reflectance spectrum were measured. Band structures and density of states were calculated. The powder second harmonic generation (SHG) effect of K2SrVB5O12 is similar to that of KH2PO4 (KDP).
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1372
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Chen Songjie,Pan Shilie,Zhao Wenwu,et al. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12[J]. Dalton Transactions,2012,41(30):9202-9208.
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文件名: a new noncentrosymmetric vanadoborate synthesis, crystal structure and characterization of k2srvb5o12.pdf
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