A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12
Chen Songjie; Pan Shilie; Zhao Wenwu; Yu Hongwei; Wu Hongping; Yang Zhihua; Yang Yun
2012
发表期刊Dalton Transactions
ISSN1477-9226
卷号41期号:30页码:9202-9208
摘要

A new noncentrosymmetric vanadoborate compound, K2SrVB5O12, is synthesized by the high temperature solution method. It crystallizes in the monoclinic space group P2(1) (no. 4) with lattice constants a = 6.618(3) angstrom, b = 8.378(4) angstrom, c = 9.974(5) angstrom, beta = 99.789(6)degrees, Z = 2. The structure consists of vanadoborate anionic layers with K+ and Sr2+ cations filling the void spaces via electrostatic interactions to form the three-dimensional network. The TG-DSC curves and the UV-Vis-NIR diffuse reflectance spectrum were measured. Band structures and density of states were calculated. The powder second harmonic generation (SHG) effect of K2SrVB5O12 is similar to that of KH2PO4 (KDP).

学科领域Chemistry
DOI10.1039/c2dt30608e
收录类别SCI
WOS记录号WOS:000306230800028
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1372
专题新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Chen Songjie,Pan Shilie,Zhao Wenwu,et al. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12[J]. Dalton Transactions,2012,41(30):9202-9208.
APA Chen Songjie.,Pan Shilie.,Zhao Wenwu.,Yu Hongwei.,Wu Hongping.,...&Yang Yun.(2012).A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12.Dalton Transactions,41(30),9202-9208.
MLA Chen Songjie,et al."A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12".Dalton Transactions 41.30(2012):9202-9208.
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