A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12
Chen Songjie; Pan Shilie; Zhao Wenwu; Yu Hongwei; Wu Hongping; Yang Zhihua; Yang Yun
2012
Source PublicationDalton Transactions
ISSN1477-9226
Volume41Issue:30Pages:9202-9208
Abstract

A new noncentrosymmetric vanadoborate compound, K2SrVB5O12, is synthesized by the high temperature solution method. It crystallizes in the monoclinic space group P2(1) (no. 4) with lattice constants a = 6.618(3) angstrom, b = 8.378(4) angstrom, c = 9.974(5) angstrom, beta = 99.789(6)degrees, Z = 2. The structure consists of vanadoborate anionic layers with K+ and Sr2+ cations filling the void spaces via electrostatic interactions to form the three-dimensional network. The TG-DSC curves and the UV-Vis-NIR diffuse reflectance spectrum were measured. Band structures and density of states were calculated. The powder second harmonic generation (SHG) effect of K2SrVB5O12 is similar to that of KH2PO4 (KDP).

Subject AreaChemistry
DOI10.1039/c2dt30608e
Indexed BySCI
WOS IDWOS:000306230800028
Citation statistics
Document Type期刊论文
Identifierhttp://ir.xjipc.cas.cn/handle/365002/1372
Collection新疆维吾尔自治区电子信息材料与器件重点实验室
材料物理与化学研究室
Corresponding AuthorPan Shilie
AffiliationChinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Chen Songjie,Pan Shilie,Zhao Wenwu,et al. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12[J]. Dalton Transactions,2012,41(30):9202-9208.
APA Chen Songjie.,Pan Shilie.,Zhao Wenwu.,Yu Hongwei.,Wu Hongping.,...&Yang Yun.(2012).A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12.Dalton Transactions,41(30),9202-9208.
MLA Chen Songjie,et al."A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12".Dalton Transactions 41.30(2012):9202-9208.
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