A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group
Yu Hongwei; Wu Hongping; Pan Shilie; Yang Zhihua; Su Xin; Zhang Fangfang
2012
发表期刊JOURNAL OF MATERIALS CHEMISTRY
ISSN0959-9428
卷号22期号:19页码:9665-9670
摘要

Single crystals of Ba3B6O11F2 have been synthesized by introducing the F- anion into the BaO-B2O3 system and the structure was determined by single-crystal X-ray diffraction. It crystallizes in the noncentrosymmetric space group P2(1) (no. 4). In the structure, a new fundamental building block, the B6O14 group, was observed. The second harmonic generation (SHG) measurement shows that Ba3B6O11F2 possesses a large SHG response about three times that of KH2PO4 (KDP) and is phase-matchable. In addition, it exhibits a wide transparency range with a short UV cut-off edge (<190 nm), which suggests that the material is a potential deep UV nonlinear optical material.

学科领域Chemistry ; Materials Science
DOI10.1039/c2jm16058g
收录类别SCI
WOS记录号WOS:000303207100036
引用统计
被引频次:106[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.xjipc.cas.cn/handle/365002/1367
专题新疆维吾尔自治区电子信息材料与器件重点实验室
通讯作者Pan Shilie
作者单位Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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Yu Hongwei,Wu Hongping,Pan Shilie,et al. A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group[J]. JOURNAL OF MATERIALS CHEMISTRY,2012,22(19):9665-9670.
APA Yu Hongwei,Wu Hongping,Pan Shilie,Yang Zhihua,Su Xin,&Zhang Fangfang.(2012).A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group.JOURNAL OF MATERIALS CHEMISTRY,22(19),9665-9670.
MLA Yu Hongwei,et al."A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group".JOURNAL OF MATERIALS CHEMISTRY 22.19(2012):9665-9670.
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