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学科主题: Chemistry ; Materials Science
题名: A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group
作者: Yu Hongwei; Wu Hongping; Pan Shilie; Yang Zhihua; Su Xin; Zhang Fangfang
通讯作者: Pan, SL
刊名: Journal of Materials Chemistry
发表日期: 2012
DOI: 10.1039/c2jm16058g
卷: 22, 期:19, 页:9665-9670
收录类别: SCI
摘要: Single crystals of Ba3B6O11F2 have been synthesized by introducing the F- anion into the BaO-B 2O3 system and the structure was determined by single-crystal X-ray diffraction. It crystallizes in the non-centrosymmetric space group P21 (no. 4). In the structure, a new fundamental building block, the B6O14 group, was observed. The second harmonic generation (SHG) measurement shows that Ba3B6O 11F2 possesses a large SHG response about three times that of KH2PO4 (KDP) and is phase-matchable. In addition, it exhibits a wide transparency range with a short UV cut-off edge (<190 nm), which suggests that the material is a potential deep UV nonlinear optical material.
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内容类型: 期刊论文
URI标识: http://ir.xjipc.cas.cn/handle/365002/1367
Appears in Collections:新疆维吾尔自治区电子信息材料与器件重点实验室_期刊论文

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作者单位: Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Yu Hongwei,Wu Hongping,Pan Shilie,et al. A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group[J]. Journal of Materials Chemistry,2012,22(19):9665-9670.
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文件名: A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group.pdf
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